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Contemporary deposition (artificial marker horizon, 3.5 years) and long-term accumulation rates (210Pb profiles, ~150 years) of sediment and associated carbon (C), nitrogen (N), and phosphorus (P) were measured in wetlands along the tidal Savannah and Waccamaw rivers in the southeastern USA. Four sites along each river spanned an upstream-to-downstream salinification gradient, from upriver tidal freshwater forested wetland (TFFW), through moderately and highly salt-impacted forested wetlands, to oligohaline marsh downriver. Contemporary deposition rates (sediment, C, N, and P) were greatest in oligohaline marsh and lowest in TFFW along both rivers. Greater rates of deposition in oligohaline and salt-stressed forested wetlands were associated with a shift to greater clay and metal content that is likely associated with a change from low availability of watershed-derived sediment to TFFW and to greater availability of a coastal sediment source to oligohaline wetlands. Long-term accumulation rates along the Waccamaw River had the opposite spatial pattern compared to contemporary deposition, with greater rates in TFFW that declined to oligohaline marsh. Long-term sediment and elemental mass accumulation rates also were 3–9× lower than contemporary deposition rates. In comparison to other studies, sediment and associated nutrient accumulation in TFFW are lower than downriver/estuarine freshwater, oligohaline, and salt marshes, suggesting a reduced capacity for surface sedimentation (short-term) as well as shallow soil processes (long-term sedimentation) to offset sea level rise in TFFW. Nonetheless, their potentially large spatial extent suggests that TFFW have a large impact on the transport and fate of sediment and nutrients in tidal rivers and estuaries.  相似文献   
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Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.  相似文献   
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Family farms have long generated income from agricultural tourism including U‐picks, wagon rides, corn mazes and petting zoos, but contemporary agricultural tourism reflects much greater sophistication in terms of product variety, services, activities, and marketing. In Michigan, farm operators have moved beyond classic products and activities and the traditional consumer base. New sources of revenue derive from classes on beer, cider, mead and wine making, yarn spinning, perfume/soap‐making, farm markets, fishing, educational classes, school tours and hospitality including weddings and on‐farm restaurants. This case study of Michigan agricultural tourism reports results from a systematic survey of 154 agritourism operations conducted throughout the state during summer and fall of 2013 with a focus on the economic benefits of the fast‐changing sector. This study summarizes tax revenues, sales and employment trends for the farm operations participating in the survey but also quantitatively assesses the contribution of agricultural tourism to Michigan's economy through an extrapolation of the sample to estimate state‐wide totals. Results from OLS multivariate regression analysis intended to identify relationships between employment, advertising and scale to gross sales per day are also reported. These analyses show the importance of agricultural tourism to rural and peri‐urban places in Michigan and throughout the nation, while raising concerns about a growing division between large and small operators and what this growing gap may mean for the future of the sector.  相似文献   
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The character and importance of uncertainty in dam safety risk analysis drives how risk assessments are used in practice. The current interpretation of uncertainty is that, in addition to the aleatory risk which arises from presumed uncertainty in the world, it comprises the epistemic aspects of irresolution in a model or forecast, specifically model and parameter uncertainty. This is true in part but it is not all there is to uncertainty in risk analysis. The physics of hazards and of failure may be poorly understood, which goes beyond uncertainty in its conventional sense. There may be alternative scenarios of future conditions, for example non-stationarity in the environment, which cannot easily be forecast. There may also be deep uncertainties of the type associated with climate change. These are situations in which analysts do not know or do not agree on the system characterisation relating actions to consequences or on the probability distributions for key parameters. All of these facets are part of the uncertainty in risk analysis with which we must deal.  相似文献   
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International Journal of Earth Sciences - The Ediacaran–Ordovician Meguma Supergroup was thrust over Avalonia basement prior to the intrusion of post-Acadian, ca. 370 Ma, S-type...  相似文献   
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Scattered data interpolation schemes using kriging and radial basis functions (RBFs) have the advantage of being meshless and dimensional independent; however, for the datasets having insufficient observations, RBFs have the advantage over geostatistical methods as the latter requires variogram study and statistical expertise. Moreover, RBFs can be used for scattered data interpolation with very good convergence, which makes them desirable for shape function interpolation in meshless methods for numerical solution of partial differential equations. For interpolation of large datasets, however, RBFs in their usual form, lead to solving an ill-conditioned system of equations, for which, a small error in the data can cause a significantly large error in the interpolated solution. In order to reduce this limitation, we propose a hybrid kernel by using the conventional Gaussian and a shape parameter independent cubic kernel. Global particle swarm optimization method has been used to analyze the optimal values of the shape parameter as well as the weight coefficients controlling the Gaussian and the cubic part in the hybridization. Through a series of numerical tests, we demonstrate that such hybridization stabilizes the interpolation scheme by yielding a far superior implementation compared to those obtained by using only the Gaussian or cubic kernels. The proposed kernel maintains the accuracy and stability at small shape parameter as well as relatively large degrees of freedom, which exhibit its potential for scattered data interpolation and intrigues its application in global as well as local meshless methods for numerical solution of PDEs.  相似文献   
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